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ZHENG BANGDING,CAI SHUIYUAN,ZHUANG MINGJIANG,JIANG LONGSHENG.MECHANISM OF URANIUM ADSORPTION ON AMIDOXIME RESIN[J].Acta Oceanologica Sinica,1985,(3):417-422
MECHANISM OF URANIUM ADSORPTION ON AMIDOXIME RESIN
MECHANISM OF URANIUM ADSORPTION ON AMIDOXIME RESIN
投稿时间:1984-03-29  修订日期:1984-10-05
DOI:
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英文关键词:
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作者单位
郑邦锭 Third Institute of Oceanography, National Bureau of Oceanography, Xiamen 
蔡水源 Third Institute of Oceanography, National Bureau of Oceanography, Xiamen 
庄明江 Third Institute of Oceanography, National Bureau of Oceanography, Xiamen 
蒋龙生 Third Institute of Oceanography, National Bureau of Oceanography, Xiamen 
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中文摘要:
      The mechanism of uranium adsorption from seawater by polyacrylamidoxime resin is investigated by means of the experiments of adsorption isotherm and adsorption rate.The uranium uptake increases with the adsorption temperature and varies with the pH of seawater.Thermochemical and kinetic calculation show that the enthalpy change (△H) and the activation energy (E) of the uranium adsorption are 42.4 42.4 kJ mol-1 and 41.2 kJ mol-1 respectively, indicating that the uranium adsorption on the resin proceeds via a certain complex chemical reaction in which the amidoxime group in the resin chelates uranyl ions.
英文摘要:
      The mechanism of uranium adsorption from seawater by polyacrylamidoxime resin is investigated by means of the experiments of adsorption isotherm and adsorption rate.The uranium uptake increases with the adsorption temperature and varies with the pH of seawater.Thermochemical and kinetic calculation show that the enthalpy change (△H) and the activation energy (E) of the uranium adsorption are 42.4 42.4 kJ mol-1 and 41.2 kJ mol-1 respectively, indicating that the uranium adsorption on the resin proceeds via a certain complex chemical reaction in which the amidoxime group in the resin chelates uranyl ions.
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