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YANG SUNKAI,LIN JIANDONG,LI XIAOBO.STUDIES ON CATALYTIC WAVE OF CHROMIUM IN SEAWATER[J].Acta Oceanologica Sinica,1985,(2):232-243
STUDIES ON CATALYTIC WAVE OF CHROMIUM IN SEAWATER
STUDIES ON CATALYTIC WAVE OF CHROMIUM IN SEAWATER
投稿时间:1984-03-23  修订日期:1984-07-10
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杨孙楷 Department of Chemistry, Xiamen University, Xiamen 
林建东 Department of Chemistry, Xiamen University, Xiamen 
李小波 Department of Chemistry, Xiamen University, Xiamen 
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中文摘要:
      In this paper, the polarographic catalytic wave of trace chromium in seawater and its mechanism are studied.In supporting electrolyte containing ethylene diamine-NaNO2-EDTA, a clear, sensitive and stable catalytic wave is obtained, and its largest peak potential in differential oscilloscopic pola-rogram is -1.7V (S.C.E).The detection limit for Cr is 1.5×10-9 M.It is unnecessary for natural seawater samples to be separated and preconcentrated, and the samples can be directly detected.Variable coefficient is 5%, and the relative error of recovery efficiency, 10%.The wave is a kind of hydrogen catalytic one with absorbability.
英文摘要:
      In this paper, the polarographic catalytic wave of trace chromium in seawater and its mechanism are studied.In supporting electrolyte containing ethylene diamine-NaNO2-EDTA, a clear, sensitive and stable catalytic wave is obtained, and its largest peak potential in differential oscilloscopic pola-rogram is -1.7V (S.C.E).The detection limit for Cr is 1.5×10-9 M.It is unnecessary for natural seawater samples to be separated and preconcentrated, and the samples can be directly detected.Variable coefficient is 5%, and the relative error of recovery efficiency, 10%.The wave is a kind of hydrogen catalytic one with absorbability.
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